Table of Characteristic IR Absorptions, podstawy chemii organicznej
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–1
bond
functional group
frequency, cm
3640–3610 (s, sh)
O–H stretch, free hydroxyl
alcohols, phenols
3500–3200 (s,b)
O–H stretch, H–bonded
alcohols, phenols
3400–3250 (m)
N–H stretch
1˚, 2˚ amines, amides
3300–2500 (m)
O–H stretch
carboxylic acids
3330–3270 (n, s)
–C
≡
C–H: C–H stretch
alkynes (terminal)
3100–3000 (s)
C–H stretch
aromatics
3100–3000 (m)
=C–H stretch
alkenes
3000–2850 (m)
C–H stretch
alkanes
2830–2695 (m)
H–C=O: C–H stretch
aldehydes
2260–2210 (v)
C
≡
N stretch
nitriles
2260–2100 (w)
–C
≡
C– stretch
alkynes
1760–1665 (s)
C=O stretch
carbonyls (general)
1760–1690 (s)
C=O stretch
carboxylic acids
1750–1735 (s)
C=O stretch
esters, saturated aliphatic
1740–1720 (s)
C=O stretch
aldehydes, saturated aliphatic
1730–1715 (s)
C=O stretch
α
,
β
–unsaturated esters
1715 (s)
C=O stretch
ketones, saturated aliphatic
1710–1665 (s)
C=O stretch
α
,
β
–unsaturated aldehydes, ketones
1680–1640 (m)
–C=C– stretch
alkenes
1650–1580 (m)
N–H bend
1˚ amines
1600–1585 (m)
C–C stretch (in–ring)
aromatics
1550–1475 (s)
N–O asymmetric stretch
nitro compounds
1500–1400 (m)
C–C stretch (in–ring)
aromatics
1470–1450 (m)
C–H bend
alkanes
1370–1350 (m)
C–H rock
alkanes
1360–1290 (m)
N–O symmetric stretch
nitro compounds
1335–1250 (s)
C–N stretch
aromatic amines
1320–1000 (s)
C–O stretch
alcohols, carboxylic acids, esters, ethers
1300–1150 (m)
C–H wag (–CH
X)
alkyl halides
2
1250–1020 (m)
C–N stretch
aliphatic amines
1000–650 (s)
=C–H bend
alkenes
950–910 (m)
O–H bend
carboxylic acids
910–665 (s, b)
N–H wag
1˚, 2˚ amines
900–675 (s)
C–H “oop”
aromatics
850–550 (m)
C–Cl stretch
alkyl halides
725–720 (m)
C–H rock
alkanes
700–610 (b, s)
–C
≡
C–H: C–H bend
alkynes
690–515 (m)
C–Br stretch
alkyl halides
m=medium, w=weak, s=strong, n=narrow, b=broad, sh=sharp
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